Authors
S Komini Babu, Hoon Taek Chung, Piotr Zelenay, Shawn Litster
Publication date
2017/8/4
Journal
Journal of The Electrochemical Society
Volume
164
Issue
9
Pages
F1037
Publisher
IOP Publishing
Description
This paper presents a two-dimensional (2D) computational model of a polymer electrolyte fuel cell (PEFC) with a platinum group metal-free (PGM-free) catalyst cathode that can significantly reduce PEFC costs by eliminating the need for expensive platinum catalysts. Due to their comparatively low volumetric activity, PGM-free cathodes are an order of magnitude thicker than their Pt-based counterpart. The resulting need for greater electrode thickness to achieve sufficient power density requires careful attention to the transport losses across the thicker cathodes. The presented model is used to correlate the composition and morphology of the cathode to PEFC performance. The model is a complete cell, continuum model that includes an advanced agglomerate model for a microstructurally consistent representation of the cathode. A unique feature of the approach is the integration of morphology and transport …
Scholar articles
SK Babu, HT Chung, P Zelenay, S Litster - Journal of The Electrochemical Society, 2017